نوع مقاله : مقاله پژوهشی

نویسندگان

1 کارشناسی ارشد، مهندسی مواد، دانشگاه صنعتی مالک اشتر، اصفهان، ایران

2 استادیار، مهندسی مواد، دانشگاه صنعتی مالک اشتر، اصفهان، ایران

چکیده

هدف از این پژوهش بررسی رفتار خوردگی پوشش‌های کامپوزیتی Fe-Ni-Cr تقویت شده توسط نانوذرات کاربید سیلیسیم و نانولوله‌های کربنی می‌باشد. در این راستا و به منظور ایجاد پوشش‌های مورد نظر، فرایند رسوب‌دهی الکتریکی در یک حمام کلریدی، در حضور و عدم حضور تقویت کننده‌های کاربید سیلیسیم و نانولوله‌های کربنی انجام شد. بررسی‌های‌ ریزساختاری توسط پراش‌سنجی پرتوایکس (XRD) و میکروسکپ‌ الکترونی روبشی گسیل میدانی (FESEM) و بررسی رفتار خوردگی به روش آنالیز پتانسیو استات در الکترولیت NaCl %5/3 انجام شد. نتایج نشان داد که پوشش آمورف- نانوکریستال Fe-Ni-Cr در چگالی جریان‌های کم به علت وجود ریزترک کمتر دارای بهترین رفتار خوردگی است. بررسی رفتار خوردگی پس از عملیات حرارتی (در دمای 250 درجه‌ی سانتی‌گراد به مدت 10 ساعت) نیز نشان داد که با انجام تبلور فاز آمورف در پوشش، مقاومت خوردگی بهبود می‌یابد. رفتار خوردگی با کامپوزیتی کردن پوشش‌های بهبود یافت به گونه‌ای که بالاترین مقاومت خوردگی در حضور نانوذرات تقویت کننده‌ی کاربید سیلیسیم در پوشش به دست آمد.

کلیدواژه‌ها

موضوعات

عنوان مقاله [English]

The comparison in corrosion behavior of Fe-Ni-Cr composite coatings reinforced by SiC nanoparticles and carbon nanotubes

نویسندگان [English]

  • Hossain Soltani 1
  • Majid Tavoosi 2

1 Department of Materials engineering, Malek-Ashtar University of Technology (MUT), , Iran

2 Department of Materials engineering, Malek-Ashtar University of Technology (MUT), Isfahan, Iran

چکیده [English]

In this study, the corrosion behavior of Fe-Ni-Cr composite coatings reinforced by SiC and carbon nanotube (CNT) has been investigated. In this regards, the electrodeposion processing has been done in a chloride bath in the presence of SiC nanoparticles and carbon nanotubes. The prepared coatings were characterized using X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM). The corrosion behavior of coatings was also examined in NaCl 3.5% electrolyte by potentiostat analysis. The results showed that, the prepared amorphous - nanocrystalline Fe-Ni-Cr coating in lower current densities has higher corrosion behavior due to lower density of micro-cracks in coat. The annealing process and the crystallization of amorphous phase (at 250oC for 10 h) had the positive effects on corrosion resistance of prepared coats. The corrosion resistance of composite coatings was higher than alloyed coatings. In this condition, the highest corrosion resistance was achieved in the presence of SiC nanoparticle in the coats.

کلیدواژه‌ها [English]

  • Electrodeposition
  • Amorphous-nanocrystalline coatings
  • Composite coatings
  • Corrosion
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