علوم و فناوری کامپوزیت

تحلیل تجربی خواص کششی نانو کامپوزیت های سه تایی پلی پروپیلن/ لاستیک نیتریل کربوکسیل شده / نانو ذرات سیلیکا به کمک روش رویه پاسخ

نوع مقاله : مقاله پژوهشی

نویسندگان

1 دانشیار، مهندسی مکانیک، دانشگاه تربیت دبیر شهید رجائی، تهران، ایران

2 کارشناس ارشد، مهندسی مکانیک، دانشگاه تربیت دبیر شهید رجائی، تهران، ایران

10.22068/jstc.2018.87223.1449

چکیده

در این تحقیق، خواص کششی، شامل استحکام کششی، مدول الاستیک و ازدیاد طول نانوکامپوزیت‌های سه تایی پلی پروپیلن/ لاستیک نیتریل کربوکسیل شده تقویت شده با نانوذرات سیلیکا بررسی شده است. برای طراحی آزمایش جهت تهیه ترکیبات از طرح Box-Behnken روش رویه پاسخ (RSM) استفاده شده است. بر اساس این طرح ازمایش 15 نمونه شامل 0، 2 و 4 درصد وزنی نانو ذرات سیلیکا 0، 3 و 6 درصد وزنی عامل سازگار کننده پلی پروپیلن مالئیکه (PP-gMA) و نیز 0، 5 و 10 درصد وزنی لاستیک نیتریل کربوکسیل شده توسط یک اکسترودر همسوگرد تهیه شدند. آزمون‌ مکانیکی کشش برای تعیین استحکام‌ کششی، مدول الاستیسیته و ازدیاد طول تا شکست ترکیبات انجام شد. نتایج نشان داد که افزودن نانو ذرات سیلیکا مدول الاستیک ( به میزان 14 درصد) و استحکام کششی ( به میزان 4 درصد) ترکیبات را افزایش می دهد. همچنین حضور لاستیک نیتریل کربوکسیل شده موجب افزایش ازدیاد طول تا شکست ( به میزان 39 درصد) ترکیبات شده است و افزایش عامل سازگار کننده پلی پروپیلن مالئیکه اندکی استحکام کششی را افزایش می دهد. همچنین مشاهده شد که لاستیک نیتریل کربوکسیل شده بیشترین تاثیر را بر استحکام کششی و ازدیاد طول تا شکست دارد و نانو ذرات سیلیکا بیشترین تاثیر بر مدول الاستیک را دارند. در پایان برای هر خاصیت کششی یک مدل رگرسیون برحسب فاکتورهای موثر ارائه شد

کلیدواژه‌ها

موضوعات

عنوان مقاله [English]

Experimental analysis of tensile properties nanocomposites based on polypropylene/ Carboxylated Nitrile Rubber /Silica nano powder by using response surface methodology

نویسندگان [English]

  • Mohammad Morad Sheikhi 1
  • Ali Sanaei 2

1 Faculty of Mechanical Engineering, Shahid Rajaee Teacher Training University, Tehran, Iran

2 Faculty of Mechanical Engineering, Shahid Rajaee Teacher Training University, Tehran, Iran

چکیده [English]

In this study, tensile properties of nanocomposites based on polypropylene/ Carboxylated Nitrile Rubber /Silica nano powder (PP/XNBR/Sic) were studied by using response surface methodology(RSM). The design of the experiment was carried out using Box-Behnken of the RSM method. The samples were produced using a co-rotating twin screw extruder including 0,2,4 Wt.% of nano particles, 0, 5, 10 Wt.% of carboxylated Nitrile Rubber and 0,3,6 Wt.% of Polypropylene-g-glycidyl Methacrylate (PP-gMA) as comptabilizer. tensile test was carried out to obtain tensile strength, elastic modulus and elongation at break of nano composites. The results showed that elastic modulus and tensile strength of nanocomposites were increased with addition of nano silica powder by 45% and 9% respectively. Also, the presence of XNBR was increased elongation at break by 39% and increasing the comptabilizer factor (PP-gMA) has slightly increased the tensile strength. In addition, it was found that XNBR has the greatest effect on tensile strength and elongation at break and silica nano powder has the greatest effect on elastic modulus. Finally, a regression model was obtained for tensile strength, elastic modulus and elongation at break, respectively

کلیدواژه‌ها [English]

  • Polypropylene
  • tensile properties
  • Silica nano powder
  • response surface methodology
  • nano composite
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علوم و فناوری کامپوزیت
دوره 6، شماره 2
شهریور 1398
صفحه 275-282
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